VIJAYASANKAR, A. V. and Aniz , C.U and Nagaraju, N (2010) Surface properties and the catalytic activity of amorphous iron aluminophosphates: Effect of Fe loading. Journal of the Korean Chemical Society, 54 (1). pp. 131-136. ISSN 1017-2548
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Iron aluminophosphates (FeAlP) with different percentage of iron were synthesized and characterized for their surfaceand bulk properties. The catalytic activity was determined in the transesterification of diethyl malonate with benzyl alcohol. Benzyl ethylmalonate and dibenzyl malonate were obtained as the only products. FeAlP with 0.025 mole % of iron was found to be distinctly different in its textural and catalytic properties. Formation of diester was found to be favored by the acid sites of intermediate strength. The presence of hydrated alumina and the polycondensed phosphates in the materials reduced the catalytic activity of iron aluminophosphates in transesterification reaction.
|Uncontrolled Keywords:||Transesterification, Benzyl malonates, Iron loading , Amorphous aluminophosphates, Transesterification, Benzyl malonates, Iron loading|
|Subjects:||Publications > Publications by Faculty > Articles > Chemistry|
|Deposited By:||Knowledge Center Christ University|
|Deposited On:||13 Dec 2011 14:33|
|Last Modified:||30 Jul 2012 11:07|
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